全文获取类型
收费全文 | 88139篇 |
免费 | 14156篇 |
国内免费 | 8895篇 |
专业分类
化学 | 61427篇 |
晶体学 | 848篇 |
力学 | 5401篇 |
综合类 | 492篇 |
数学 | 10413篇 |
物理学 | 32609篇 |
出版年
2024年 | 90篇 |
2023年 | 1720篇 |
2022年 | 1894篇 |
2021年 | 2840篇 |
2020年 | 3530篇 |
2019年 | 3291篇 |
2018年 | 2844篇 |
2017年 | 2638篇 |
2016年 | 4032篇 |
2015年 | 3904篇 |
2014年 | 4685篇 |
2013年 | 6191篇 |
2012年 | 7843篇 |
2011年 | 8166篇 |
2010年 | 5486篇 |
2009年 | 5266篇 |
2008年 | 5751篇 |
2007年 | 5237篇 |
2006年 | 4807篇 |
2005年 | 3965篇 |
2004年 | 3239篇 |
2003年 | 2587篇 |
2002年 | 2404篇 |
2001年 | 1995篇 |
2000年 | 1760篇 |
1999年 | 1858篇 |
1998年 | 1550篇 |
1997年 | 1473篇 |
1996年 | 1467篇 |
1995年 | 1198篇 |
1994年 | 1099篇 |
1993年 | 926篇 |
1992年 | 819篇 |
1991年 | 693篇 |
1990年 | 630篇 |
1989年 | 475篇 |
1988年 | 433篇 |
1987年 | 340篇 |
1986年 | 328篇 |
1985年 | 310篇 |
1984年 | 216篇 |
1983年 | 182篇 |
1982年 | 135篇 |
1981年 | 115篇 |
1980年 | 116篇 |
1978年 | 68篇 |
1977年 | 78篇 |
1976年 | 70篇 |
1974年 | 67篇 |
1973年 | 75篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
应用互补集成经验模态分解(CEEMD)方法对香港1997―2018年的住宅价格月度数据进行了分解,将经过重构后的数据分成高频序列、低频序列与残差项。将BP多断点检测应用于低频序列,并结合样本时段内的重大事件进行实证分析。结果表明:1997年亚洲金融风暴对房价的影响大于2008年金融危机;外部经济体的救市政策间接地影响香港房价;在经济不景气的大环境下“孙九招”政策没有立即见效;资本投资者入境计划、住房供给调整与按揭贷款调整对房价的影响较为显著;税收调整对房价影响不显著、对交易量影响显著;SARS爆发使住宅价格下降约1%。 相似文献
32.
Hongling Yu Heyong Wang Galia Pozina Chunyang Yin Xiao-Ke Liu Feng Gao 《Chemical science》2020,11(41):11338
Metal halide perovskites have demonstrated impressive properties for achieving efficient monochromatic light-emitting diodes. However, the development of white perovskite light-emitting diodes (PeLEDs) remains a big challenge. Here, we demonstrate a single-emissive-layer all-perovskite white PeLED using a mixed halide perovskite film as the emissive layer. The perovskite film consists of separated mixed halide perovskite phases with blue and red emissions, which are beneficial for suppressing halide anion exchange and preventing charge transfer. As a result, the white PeLED shows balanced white light emission with Commission Internationale de L''Eclairage coordinates of (0.33, 0.33). In addition, we find that the achievement of white light emission from mixed halide perovskites strongly depends on effective modulation of the halide salt precursors, especially lead bromide and benzamidine hydrochloride in our case. Our work provides very useful guidelines for realizing single-emissive-layer all-perovskite white PeLEDs based on mixed halide perovskites, which will spur the development of high-performance white PeLEDs.We demonstrated a single-emissive-layer all-perovskite white light-emitting diode based on a mixed halide perovskite film. 相似文献
33.
34.
The indentation technique is widely used in measuring the mechanical properties of soft matter at the microscale or nanoscale,but still faces challenges by these unique properties as well as the consequent strong surface adhesion, including the strong nonlinear effect, unclear judgment of the contact point, difficulties in estimating the contact area, and the risk of the indenter piercing the sample. Here we propose a two-step method to solve these problems: lay a hard film on a soft matter, and obtain the viscoelastic properties of this soft matter through the indentation response of this composite structure. We first establish a theoretical indentation model of the hard film-soft substrate system based on the theory of plates, elastic-viscoelastic correspondence principle and Boltzmann superposition principle. To verify the correctness of this method, we measure the mechanical properties of the methyl vinyl silicone rubber(MVSR) covered by a Cu nanofilm. Finally, we test the effectiveness and error sensitivity of this method with the finite element method(FEM). The results show that our method can accurately measure the mechanical properties of soft matter, while effectively circumventing the problems of the traditional indentation technique. 相似文献
35.
36.
Jing Zhihong Ling Baoping Yu Yang Qi Wei Zhang Shufang 《Journal of Sol-Gel Science and Technology》2015,73(1):112-117
Journal of Sol-Gel Science and Technology - A novel gas sensing material, La–Y co-doped TiO2 nanoparticles, was synthesized by sol–gel method and applied to detect organic pollutants... 相似文献
37.
38.
39.
Richiro Ushimaru Zhang Chen Houyuan Zhao Po-hsun Fan Prof. Dr. Hung-wen Liu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(9):3586-3590
Albomycin δ2 is a sulfur-containing sideromycin natural product that shows potent antibacterial activity against clinically important pathogens. The l -serine-thioheptose dipeptide partial structure, known as SB-217452, has been found to be the active seryl-tRNA synthetase inhibitor component of albomycin δ2. Herein, it is demonstrated that AbmF catalyzes condensation between the 6′-amino-4′-thionucleoside with the d -ribo configuration and seryl-adenylate supplied by the serine adenylation activity of AbmK. Formation of the dipeptide is followed by C3′-epimerization to produce SB-217452 with the d -xylo configuration, which is catalyzed by the radical S-adenosyl-l -methionine enzyme AbmJ. Gene deletion suggests that AbmC is involved in peptide assembly linking SB-217452 with the siderophore moiety. This study establishes how the albomycin biosynthetic machinery generates its antimicrobial component SB-217452. 相似文献
40.
Jie Lu Ju-Kang Wu Yao Jiang Dr. Peng Tan Lin Zhang Yu Lei Prof. Xiao-Qin Liu Prof. Lin-Bing Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6490-6496
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. 相似文献